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- W2059905574 abstract "The heterobimetallic complex syn-[Cr(CO)3(μ,η:η-indenyl)Rh(COD)] was obtained of syn-[Cr(CO)3(μ,η:η-indenyl(Rh(CO)2] with COD. The stereochemistry was retained in the exchange reaction as confirmed by 1H and 13C NMR measurements and by X-ray diffractometric analysis. In spite of great distortion, the COD complex is quite stable. An unusual bonding interaction between the hybrid CO orbitals of the Cr(CO)3 group and the s-orbital of methine hydrogen atoms of COD is inferred on the basis of spectroscopic and X-ray structural data." @default.
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- W2059905574 date "1995-04-01" @default.
- W2059905574 modified "2023-10-17" @default.
- W2059905574 title "Heterobimetallic indenyl complexes. Synthesis and structure of syn-[Cr(CO)3(μ, η:η-indenyl)Rh(COD)]" @default.
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- W2059905574 doi "https://doi.org/10.1016/0022-328x(94)05280-o" @default.
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