Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059968265> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W2059968265 endingPage "2871" @default.
- W2059968265 startingPage "2866" @default.
- W2059968265 abstract "The two dimensional conformational spaces available for acetoxymethyl groups in carbohydrates are reported. The studies were performed on two molecules differing in their C-4 configurations, i.e. gluco and galacto. The acetoxymethyl group was assigned a mean geometry derived from the computation of 19 equivalent groups as found in pertinent acetylated carbohydrates. The internal energy calculations were performed by including the partitioned contributions arising from the non-bonded energies, electrostatic interactions, and torsion energy. An instability rating of 3 kcal/mol was assigned to conformations involving peri interactions, i.e., trans–gauche and gauche–gauche forms in gluco and galacto carbohydrates, respectively. The results which are best described in term of topology show that several conformations corresponding to the trans and gauche states of the C—O single bond are preferred. However, significant shifts from perfect staggering are observed. The predicted regions of low energy are found to be in good agreement with experimental data from crystal structures of acetylated carbohydrates." @default.
- W2059968265 created "2016-06-24" @default.
- W2059968265 creator A5011046749 @default.
- W2059968265 creator A5021533289 @default.
- W2059968265 creator A5037146137 @default.
- W2059968265 date "1978-11-15" @default.
- W2059968265 modified "2023-09-23" @default.
- W2059968265 title "Rotamers arising from restricted motions and electromc interactions of acetoxymethyl groups in carbohydrates" @default.
- W2059968265 cites W2058805983 @default.
- W2059968265 doi "https://doi.org/10.1139/v78-471" @default.
- W2059968265 hasPublicationYear "1978" @default.
- W2059968265 type Work @default.
- W2059968265 sameAs 2059968265 @default.
- W2059968265 citedByCount "31" @default.
- W2059968265 countsByYear W20599682652014 @default.
- W2059968265 crossrefType "journal-article" @default.
- W2059968265 hasAuthorship W2059968265A5011046749 @default.
- W2059968265 hasAuthorship W2059968265A5021533289 @default.
- W2059968265 hasAuthorship W2059968265A5037146137 @default.
- W2059968265 hasConcept C141071460 @default.
- W2059968265 hasConcept C147597530 @default.
- W2059968265 hasConcept C178790620 @default.
- W2059968265 hasConcept C185592680 @default.
- W2059968265 hasConcept C18705241 @default.
- W2059968265 hasConcept C2781311116 @default.
- W2059968265 hasConcept C32909587 @default.
- W2059968265 hasConcept C71240020 @default.
- W2059968265 hasConcept C71924100 @default.
- W2059968265 hasConcept C77461463 @default.
- W2059968265 hasConcept C8010536 @default.
- W2059968265 hasConceptScore W2059968265C141071460 @default.
- W2059968265 hasConceptScore W2059968265C147597530 @default.
- W2059968265 hasConceptScore W2059968265C178790620 @default.
- W2059968265 hasConceptScore W2059968265C185592680 @default.
- W2059968265 hasConceptScore W2059968265C18705241 @default.
- W2059968265 hasConceptScore W2059968265C2781311116 @default.
- W2059968265 hasConceptScore W2059968265C32909587 @default.
- W2059968265 hasConceptScore W2059968265C71240020 @default.
- W2059968265 hasConceptScore W2059968265C71924100 @default.
- W2059968265 hasConceptScore W2059968265C77461463 @default.
- W2059968265 hasConceptScore W2059968265C8010536 @default.
- W2059968265 hasIssue "22" @default.
- W2059968265 hasLocation W20599682651 @default.
- W2059968265 hasOpenAccess W2059968265 @default.
- W2059968265 hasPrimaryLocation W20599682651 @default.
- W2059968265 hasRelatedWork W1964201918 @default.
- W2059968265 hasRelatedWork W1971620960 @default.
- W2059968265 hasRelatedWork W2012022888 @default.
- W2059968265 hasRelatedWork W2054883196 @default.
- W2059968265 hasRelatedWork W2123703443 @default.
- W2059968265 hasRelatedWork W2151321415 @default.
- W2059968265 hasRelatedWork W2315087761 @default.
- W2059968265 hasRelatedWork W2345527854 @default.
- W2059968265 hasRelatedWork W3112646615 @default.
- W2059968265 hasRelatedWork W4308477110 @default.
- W2059968265 hasVolume "56" @default.
- W2059968265 isParatext "false" @default.
- W2059968265 isRetracted "false" @default.
- W2059968265 magId "2059968265" @default.
- W2059968265 workType "article" @default.