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- W2059969006 abstract "Reported is a one-pot transformation of 2-iodobenzoic acid into 2,3- or 3-substituted indole derivatives via Curtius rearrangement/Pd-catalyzed indolization with acetylenic or aliphatic aldehyde substrates. Varying the base, either alkynes or aldehydes (ketones) could be used as substrates affording indoles in moderate to good yields. Treatment of the Curtius intermediates with amines led to the formation of ureas, which were subsequently cyclized to afford acylated indoles in poor to modest yields. In both reaction sequences, the substrate scope was sufficiently studied." @default.
- W2059969006 created "2016-06-24" @default.
- W2059969006 date "2008-02-21" @default.
- W2059969006 modified "2023-09-25" @default.
- W2059969006 title "Curtius-Rearrangement Approach to 2,3-Substituted Indoles" @default.
- W2059969006 doi "https://doi.org/10.1055/s-2008-1042747" @default.
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