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- W2060006868 abstract "The 69Ga3 cluster has been prepared and trapped in an adamantane matrix at 77 K using a rotating cryostat. It has been examined by EPR spectroscopy and has three magnetically equivalent 69Ga nuclei. Attempts to simulate the powder spectrum recorded at 4 K gave ‖a⊥(69)‖=240±3 MHz, g⊥=1.9651±0.002, and g∥=1.9568±0.0025. Spectra were less sensitive to the magnitude of ‖a∥(69)‖ but a value of 120±10 MHz appeared to give the best fit. There were no other fine structure lines in the spectrum suggesting that the electronic ground state for this group 13 trimer is probably 2A1′ although a 4A2 ground state cannot be completely excluded." @default.
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- W2060006868 date "1994-02-15" @default.
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- W2060006868 title "Electron paramagnetic resonance spectroscopic study of the gallium trimer, Ga3" @default.
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- W2060006868 doi "https://doi.org/10.1063/1.466380" @default.
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