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• W2060011611 abstract "The synthesis and photophysics of two new donor-acceptor conjugated A-B type copolymers based on conjugated 2,6-disubstitued-4-phenyl-quinoline and 2-substitued-4-phenyl-quinoline, and 9,9-dialkyl-fluorene linked through the 1,4 and 1,3,5 phenyl rings via the Friedländer condensation and Suzuki coupling reaction are presented. The band gap energy of the polymers 1 and 2 measured from the thin films were 430 nm and 380 nm corresponding to 2.88 eV and 3.26 eV, respectively. The photoluminescence (PL) spectra of the thin films of the polymers 1 and 2 showed maximum peaks at 427 and 397 nm corresponding to the deep blue and UV ranges respectively. The red shift of the polymer 1 relative to the polymer 2 can be accounted for by the increased conjugation length because the quinoline unit is oriented to include the phenyl ring in the backbone of polymer 1 . Both polymers have similar trends of irreversible oxidation. The ionization energy of polymers 1 and 2 were measured by cyclic voltammetry (CV) and were found to be 5.60 and 5.65 eV, respectively." @default.
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• W2060011611 date "2006-12-25" @default.
• W2060011611 modified "2023-10-18" @default.
• W2060011611 title "Synthesis and Photophysics of New Donor-Acceptor Copolymers Based on Fluorene and Phenylquinolines" @default.
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• W2060011611 doi "https://doi.org/10.1080/07370650601013104" @default.
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