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• W2060052893 abstract "Ultraviolet photoelectron spectra (UPS) of ${mathrm{LaC}}_{82}$ questioning whether the La atom is inside the C cage or not are measued for the first time. The UPS of ${mathrm{LaC}}_{82}$ is analogous to those ${mathrm{ofC}}_{82}$ but there is a critical differnce in the region just below the Fermi level. It is on appearance of two new peak components at 0.9 and 1.6 eV with the intensity ratio of 1:2 in the UPS of ${mathrm{LaC}}_{82}$. Their origin is the transfer of three electrons from La to ${mathrm{C}}_{82}$ to form the electronic structure of ${mathrm{La}}^{+3}$${mathrm{C}}_{82}^{mathrm{ensuremath{-}}3}$. Present results combined with theoretical calculations on the position of the La atom in the molecule assert an encapsulation of the La atom inside the C cage." @default.
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• W2060052893 date "1993-12-20" @default.
• W2060052893 modified "2023-10-10" @default.
• W2060052893 title "Electronic structure of metallofullerene<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>LaC</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>: Electron transfer from lanthanum to<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>C</mml:mi></mml:mrow><mml:mrow><mml:mn>82</mml:mn></mml:mrow…" @default.
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• W2060052893 doi "https://doi.org/10.1103/physrevlett.71.4261" @default.
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