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- W2060072052 abstract "trans-β-Hydroxypipecolic acids of both l- and d-series, l-1 and d-1, have been straightforwardly prepared in 14% and 15% yields, respectively, starting from glyceraldehyde imines d-7 and l-7 as useful three-carbon chirons. The key feature of these parallel syntheses lies on the highly diastereoselective character of the initial coupling manoeuver between silyloxy furan TBSOF and imines 7, which ultimately accounts for the relative, and hence absolute configuration of the target pipecolic acids." @default.
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- W2060072052 date "1997-09-01" @default.
- W2060072052 modified "2023-10-16" @default.
- W2060072052 title "Total synthesis of both enentiomers of trans-β-hydroxyppecolic acid" @default.
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- W2060072052 doi "https://doi.org/10.1016/s0957-4166(97)00344-3" @default.
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