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- W2060086983 abstract "Raman scattering and complementary high-resolution electron-energy-loss spectroscopy (HREELS) have been utilized to study intermolecular dynamics in ${mathit{A}}_{mathit{x}}$${mathrm{C}}_{60}$ thin-film systems for x=3, 4, and 6. For ${mathrm{K}}_{3}$${mathrm{C}}_{60}$, disorder-induced Raman scattering on polycrystalline films and HREELS of ordered epitaxial films on Cu(111) yield information on tetrahedral- and octahedral-site alkali-metal motions, respectively. In ${mathrm{K}}_{4}$${mathrm{C}}_{60}$, disordered films yield broad Raman and HREELS spectra that differ due to coupling parameter variations. In contrast, ordered ${mathrm{K}}_{6}$${mathrm{C}}_{60}$ and ${mathrm{Rb}}_{6}$${mathrm{C}}_{60}$ indicate q=0 response functions. Polarized and depolarized Raman scattering provide additional information on ${mathit{A}}_{mathit{g}}$ and ${mathit{T}}_{mathit{g}}$ modes." @default.
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- W2060086983 date "1995-05-01" @default.
- W2060086983 modified "2023-09-26" @default.
- W2060086983 title "Intermolecular Raman scattering and electron-energy-loss studies ofAxC60" @default.
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- W2060086983 doi "https://doi.org/10.1103/physrevb.51.11393" @default.
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