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• W2060132810 abstract "Methacrylic polymers bearing in the side-chain the electron donor–acceptor conjugated trans-azoaromatic chromophore linked to the main chain through a chiral moiety of one prevailing absolute configuration, have been prepared and investigated as materials suitable to reversible optical storage. In addition to the induction of a significant birefringence, upon irradiation of the polymeric film with linearly polarized (LP) light, combined with a relevant stability and reproducibility after repeated writing–erasing cycles with linearly and circularly polarized (CP) light, respectively, the material exhibits inversion of chirality when the erasing step is performed with one-handed CP light of the opposite sense with respect to the original chirality handedness assumed by the material as a consequence of its intrinsically chiral structure. The process appears to be reversible, and the material may re-assume the original screw sense by irradiating with circularly polarized light of the appropriate sense, regardless previous ordering by irradiation with LP light has been performed. The sense of chirality assumed by the material upon irradiation with one-handed CP light is unaffected by heating; and annealing of the film at higher temperature, above the glass transition, produces an enhancement of the dichroic bands related to the electronic transitions of the azoaromatic chromophore." @default.
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• W2060132810 date "2003-06-01" @default.
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• W2060132810 title "Reversible chirality inversion of photochromic methacrylic polymers upon irradiation with one-handed circularly polarized light" @default.
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• W2060132810 doi "https://doi.org/10.1016/s0379-6779(02)01302-4" @default.
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