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- W2060152015 abstract "The Claisen rearrangement of allyl o- or p-hydroxyphenyl ether is catalyzed by alkali metal salts. The mechanism of the catalytic effect is different from that by Lewis acids such as zinc chloride. It is considered that the hydroxyl group is dissociated into phenoxide ion –O− with loss of its proton through attack by the anion residue of an alkali metal salt. Thus, the catalytic effect is attributable to a strong electron-releasing effect of phenoxide ion –O−. Furthermore, for the o-isomer, an intramolecular repulsion between the phenoxide ion –O− and the ethereal oxygen operates." @default.
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- W2060152015 date "1989-12-01" @default.
- W2060152015 modified "2023-09-23" @default.
- W2060152015 title "Study on the Claisen Rearrangement. VI. Catalytic Effect of Alkali Metal Salts on the Claisen Rearrangement of Allyl<i>o</i>- or<i>p</i>-Hydroxyphenyl Ether" @default.
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- W2060152015 doi "https://doi.org/10.1246/bcsj.62.3835" @default.
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