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• W2060180360 abstract "Condensation of mono N-substituted chiral ethylenediamines and pyridine-2-methoxyimidate gives new chiral pyridine imidazolines (1a–c). These react with [RuCl2(mes)]2 (mes = 1,3,5-trimethyl benzene) in the presence of NaSbF6 to give complexes [RuCl(L)(mes)][SbF6] (5a–c) which after treatment with AgSbF6 are enantioselective catalysts for the Diels-Alder reaction of methacrolein and cyclopentadiene. The imidazoline catalysts are less selective than the corresponding oxazoline ones. Compounds 1a, 5b and 5c have been characterised by X-ray crystallography." @default.
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• W2060180360 date "2006-08-01" @default.
• W2060180360 modified "2023-09-30" @default.
• W2060180360 title "Chiral pyridine imidazolines from C1-symmetric diamines: Synthesis, arene ruthenium complexes and application as asymmetric catalysis for Diels-Alder reactions" @default.
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• W2060180360 doi "https://doi.org/10.1016/j.jorganchem.2006.04.028" @default.
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