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- W2060198386 abstract "Single-walled carbon nanotubes (SWNTs) and C60-encapsulated SWNTs (C60@SWNTs) are introduced to Rusensitized photoelectrochemical cells (PECs), and photocurrents are compared between two cells, i.e., an RuL2(NCS)2/DAPV/SWNTs/ITO cell and an RuL2(NCS)2/DAPV/C60@SWNTs/ITO cell. [L = 2,2'bipyridine-4,4'-dicarboxylic acid, DAPV = di-(3-aminopropyl)-viologen, and ITO = indium-tin oxide] The photocurrents are increased by 70.6% in the presence of C60@SWNTs. To explain the photocurrent increase, the reverse-field emission method is used, i.e., RuL2(NCS)2/DAPV/SWNTs/ITO cell (or RuL2(NCS)2/DAPV/ C60@SWNTs/ITO cell) as an anode and a counter electrode Pt as a cathode in the external electric field. The improved field emission properties, i.e., β (field enhancement factor) and emission currents in the reverse-field emission with C60@SWNTs indicate the enhancement of the PEC electric field, which implies the improvement of the electron transfer rate along with the reduced charge recombination in the cell." @default.
- W2060198386 created "2016-06-24" @default.
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- W2060198386 date "2012-08-20" @default.
- W2060198386 modified "2023-10-12" @default.
- W2060198386 title "Enhancement of Photocurrent Generation by C<sub>60</sub>-encapsulated Single-walled Carbon Nanotubes in Ru-sensitized Photoelectrochemical Cell" @default.
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- W2060198386 doi "https://doi.org/10.5012/bkcs.2012.33.8.2689" @default.
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