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- W2060221530 abstract "Multifrequency (24−94 GHz) and variable temperature (5−300 K) single-crystal electron paramagnetic resonance (EPR) studies have been used to probe the magnetic exchange pathway, spin dynamics, and assignment of the principal magnetic axes in the organic molecular magnet 4-(4‘-cyano-tetrafluorophenyl)-1,2,3,5-dithiadiazolyl, β-p-NCC6F4CNSSN. Orientation-dependent studies indicate that the dominant exchange pathway is perpendicular to the crystallographic c-axis, while variable-temperature studies confirm the ordering transition at 36 K and illustrate that the sublattice magnetization is essentially saturated below 15 K. The orientation dependence of the EPR spectra at 5 K has confirmed the easy axis of magnetization to be parallel to the b-axis and allowed the first determination of the intermediate and hard axes of magnetization as parallel to c- and a-axes, respectively." @default.
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- W2060221530 date "2003-11-27" @default.
- W2060221530 modified "2023-10-17" @default.
- W2060221530 title "Antiferromagnetic Resonance Studies on the Spin-Canted Molecular Magnet β-<i>p</i>-NCC<sub>6</sub>F<sub>4</sub>CNSSN" @default.
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- W2060221530 doi "https://doi.org/10.1021/jp037049m" @default.
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