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- W2060239436 abstract "Abstract The electrochemistry of the Cu(II)/Cu(I) couple under nitrogen and carbon monoxide has been investigated in the ambient-temperature molten salt AlCl 3 :MEICl (MEICl = 1-methyl-3-ethyl-imidazolium chloride) at a 250 μm tungsten disk electrode. Under nitrogen, the couple exhibits reversible electrode kinetics; however, under carbon monoxide, a Cu(I)CO complex is formed and the Cu(II)/Cu(I) couple displays asymmetric, quasi-reversible electrode kinetics. Pulse voltammetric data were fit with a nonlinear least-squares fitting program to give an apparent standard rate constant ( k 0 a ) of 1.5 × 10 −3 cm s −1 and an anodic transfer coefficient (β) of 0.12–0.17 for the oxidation of the Cu(I)CO complex. The change from reversible to quasi-reversible electrode kinetics is attributed to the concurrent dissociation of the Cu(I)CO bond during the electron transfer process." @default.
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- W2060239436 date "1993-05-01" @default.
- W2060239436 modified "2023-09-27" @default.
- W2060239436 title "Asymmetric electrode kinetics induced by concurrent metal-ligand bond dissociation" @default.
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