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- W2060250680 endingPage "515" @default.
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- W2060250680 abstract "Bond polarizability derivatives obtained from Raman intensities, are examined for a wide range of bond types, including several new values determined in this study: F2, Cl2, BF3, CF4, NF3, SiF4, SF6 (gas phase) and BF4−, PF6−, AsF6−, SiF6−, GeF62− (aqueous solution). A new delta function potential model equation, αu′= (0.1)χr3(n/2) in which the delta function strength is represented simply by the electronegativity of the more electronegative atom in the bond, gives better agreement with the entire range of data than previous, more complicated formulations. The equation fails for hydrides and for multiple bonds; in both cases the calculated value of αu′ is too low. Pi bonds evidently contribute more to αu′ than do sigma bonds, but no single ratio of the two contributions is generally applicable. It seems likely that the r3 dependence breaks down at the short bond distances found for hydrides; the discrepancy can be corrected by inclusion of an empirical factor of 3.5 per hydrogen atom in the bond." @default.
- W2060250680 created "2016-06-24" @default.
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- W2060250680 date "1977-01-01" @default.
- W2060250680 modified "2023-10-17" @default.
- W2060250680 title "Raman intensities and bond orders—A simplified delta function equation" @default.
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- W2060250680 doi "https://doi.org/10.1016/0584-8539(77)80063-9" @default.
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