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• W2060330717 startingPage "267" @default.
• W2060330717 abstract "The inhomogeneous electric field of a neighbouring polar molecule exerts a special induction in an unsaturated hydrocarbon, giving rise to more negative excess properties. This effect has been investigated for the excess Gibbs energy gE and the excess volume vE for mixtures of the polar components 1-chlorobutane, 2-butanone, and ethanenitrile with the four hydrocarbons cyclohexane, cyclohexene, 1,4-cyclohexadiene, and benzene at 293.15 K and 313.15 K. The measurements of gE were done by VLE (static vapour pressures by a continuous dilution apparatus) and checked by LLE for the systems with phase separation. Excess volumes were determined via a vibratim tube densimeter. Equation of state calculations enabled the evaluation of the interaction virial coefficient B12. The special induction effect, which shows up strongly in gE and vE of the liquid mixtures, is only weakly reflected in B12." @default.
• W2060330717 created "2016-06-24" @default.
• W2060330717 creator A5019853642 @default.
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• W2060330717 date "1989-10-01" @default.
• W2060330717 modified "2023-09-27" @default.
• W2060330717 title "Excess properties of mixtures of polar components and hydrocarbons of varying local polarisability" @default.
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• W2060330717 doi "https://doi.org/10.1016/0378-3812(89)80295-x" @default.
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