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• W2060336545 endingPage "13348" @default.
• W2060336545 startingPage "13341" @default.
• W2060336545 abstract "Laser pulse photolysis experiments have shown that the triplet excited-state of 1,2,3,4-tetraphenylnaphthalene (TPN) is one of the primary intermediates of the photochemical transformation of 7,7'-dimethylgerma-1,4,5,6-tetraphenyl-2,3-benzo-norbornadiene (GNB) in hexane solution. The molar absorption of T-T absorption and the quantum yield of the intersystem crossing of TPN were determined from the triplet-triplet energy transfer. The scheme of GNB photocleavage has been suggested where the triplet excited TPN originated from the triplet state of biradical through cleavage of the second C-Ge bond, the latter being generated from the excited singlet state of the initial GNB after the cleavage of the first C-Ge bond and the intersystem crossing. Other channels of GNB's chemical transformation have been discussed." @default.
• W2060336545 created "2016-06-24" @default.
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• W2060336545 date "2006-11-29" @default.
• W2060336545 modified "2023-10-05" @default.
• W2060336545 title "Fast Processes and Intermediates in Photochemistry of 7-Dimethyl-germanorbornadiene" @default.
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• W2060336545 doi "https://doi.org/10.1021/jp0604950" @default.
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• W2060336545 hasPublicationYear "2006" @default.
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