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- W2060340975 abstract "The mechanisms of formation and decomposition of the ferroelectric perovskite PZN [Pb(Zn1/3Nb2/3)O3] were examined. The formation of perovskite PZN from the excess molten PbO environment is characterized by an inititial rapid formation of pyrochlore phase, followed by a subsequent reaction between the intermediate pyrochlore phase, ZnO, and liquid PbO to produce perovskite phase. The pure perovskite PZN crystal prepared by the PbO flux method is thermodynamically unstable over a wide range of temperature (600° to 1400°C), yielding pyrochlore phase and PbO as the decomposition products. The decomposition reaction of perovskite PZN proceeded uniformly with a spatial homogeneity throughout the specimen. The estimated activation energy of the decomposition reaction is approximatley 18 kcal/mol." @default.
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- W2060340975 date "1992-01-01" @default.
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- W2060340975 title "Thermodynamic Stability and Mechanisms of Formation and Decomposition of Perovskite Pb(Zn<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>Prepared by the PbO Flux Method" @default.
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- W2060340975 doi "https://doi.org/10.1111/j.1151-2916.1992.tb05446.x" @default.
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