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• W2060374745 abstract "The mechanism of the solvent-free solid-state dibenzophenazine synthesis by dry co-grinding in a vibratory ball-mill has been investigated. The kinetics of the transformation was followed by HPLC and granulometry evolutions were quantified after co-grinding. The mechanism assumed involves a quinone imine intermediate formed during the first step of the reaction (addition of an amino group to a carbonyle) which is favored by the orbital overlaps between reagents. A water molecule formation occurs during the following step and hydrogen bonds are formed: the water molecule forms a bridge between the reactive centers of the quinone imine, and acts as a catalyst for the completion of the reaction. A push–pull mechanism involving the water bridge is proposed: the energy barrier is reduced by this way. Finally, two thermodynamic drivers favor the dibenzophenazine formation: the increased aromacity number in the product and the stabilization, thanks to water molecules." @default.
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• W2060374745 date "2013-05-01" @default.
• W2060374745 modified "2023-10-16" @default.
• W2060374745 title "Greener pharmacy using solvent-free synthesis: Investigation of the mechanism in the case of dibenzophenazine" @default.
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• W2060374745 doi "https://doi.org/10.1016/j.powtec.2012.07.009" @default.
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