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- W2060375073 abstract "Quantitative reaction between copper(I) cyanide and triphenyl phosphite forms copper(I) complex [(P(OPh)3)4Cu4(CN)4] (1). X-Ray crystal structure shows a catenarian polymer of tandem interconnected copper cyanide, with C and N connecting to proximal Cu atoms. The Cu atoms adopt two different conformations:one exhibits linear construction, while the other exhibits distorted tetrahedral geometry through coordinating to two cyano groups and the P donors of triphenyl phosphite molecules. The feature of 1 is the propagation pattern of two- and four-coordination along with the chain. IR and electronic absorption spectra also confirm the established single crystal structure. Thermal analysis indicates that 1 has a high thermal stability. 3-D fluorescence result shows the middle absorption peaks with the maximum excitement and emission wavelength 342 and 350 nm, respectively. Cyclic voltammogram in DMSO, DMF and MeCN gives a midpoint voltage of −0.003, 0.061 and 0.137 V versus SCE, respectively, showing the different solvent virtue on reduction potential." @default.
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- W2060375073 date "2006-09-01" @default.
- W2060375073 modified "2023-10-18" @default.
- W2060375073 title "A Novel Catenarian Cyano(triphenyl phosphite) Copper(I) Complex: Synthesis, Crystal Structure, Thermal, Voltammetric and Spectral Properties†" @default.
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- W2060375073 doi "https://doi.org/10.1002/cjoc.200690215" @default.
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