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- W2060399275 abstract "Abstract Direct oxidative intercalation of bis(fluorosulfuryl)peroxide, S 2 O 6 F 2 into graphite has been reported (1) to yield a binary graphite salt of the composition. C 8 SO 3 F. We report on reactions of this compound. Solvolysis in HSO 3 CF 3 yields quantitatively C 12 SO 3 CF 3 while with SbF 5 , C 8 SbF 6 is formed. The intercalation of BrSO 3 F and ClSO 3 F is studied as well. In the first case C 12 BrSO 3 F is formed. Subsequent reaction with S 2 O 6 F 2 yields C 16 Br(SO 3 F) 3 . With ClSO 3 F no stable chlorine containing intercalates form and materials of the composition C 10 SO 3 F result instead. The results of Raman, IR, X-ray diffraction and 19 F-nmr are discussed." @default.
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- W2060399275 date "1982-09-01" @default.
- W2060399275 modified "2023-09-27" @default.
- W2060399275 title "Fluorosulfate containing intercalation compounds" @default.
- W2060399275 doi "https://doi.org/10.1016/s0022-1139(00)85361-0" @default.
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