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- W2060472212 abstract "A new scheme to calculate the surface tension of real fluids at a wide range of temperature (from the triple point to the critical point) is proposed, the input being only the known value of surface tension at the triple point. The calculation is based on a density functional theory proposed in an earlier work (J. Chem. Phys 135, 124710 (2011)) which uses a double well type Helmholtz free energy density functional and a model density profile for the interface along the lines of van der Waals and Cahn and Hilliard density functional formalism of the interface. The methodology has been used for the calculation of surface tension of different fluids such as water, heavy water as well as argon and very good agreement between the calculated and experimental values is observed. The advantage of this approach is that the surface tension of the real fluids can be accurately and analytically obtained without handling the detailed microscopic features of the fluids." @default.
- W2060472212 created "2016-06-24" @default.
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- W2060472212 date "2012-11-01" @default.
- W2060472212 modified "2023-09-23" @default.
- W2060472212 title "Density functional theory of surface tension of real fluids using a double well type Helmholtz free energy functional: application to water and heavy water" @default.
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- W2060472212 doi "https://doi.org/10.1080/00268976.2012.737939" @default.
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