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• W2060492363 endingPage "3547" @default.
• W2060492363 startingPage "3542" @default.
• W2060492363 abstract "Detailed voltammetric results for five uranyl coordination complexes are presented and analyzed using digital simulations of the voltammetric data to extract thermodynamic (E1/2) and heterogeneous electron-transfer kinetic (k0 and α) parameters for the one-electron reduction of UO22+ to UO2+. The complexes and their corresponding electrochemical parameters are the following: [UO2(OH2)5]2+ (E1/2 = −0.169 V vs Ag/AgCl, k0 = 9.0 × 10-3 cm/s, and α = 0.50); [UO2(OH)5]3- (−0.927 V, 2.8 × 10-3 cm/s, 0.46); [UO2(C2H3O2)3]- (−0.396 V, ∼0.1 cm/s, ∼0.5); [UO2(CO3)3]4- (−0.820 V, 2.6 × 10-5 cm/s, 0.41); [UO2Cl4]2- (−0.065 V, 9.2 × 10-3 cm/s, 0.30). Differences in the E1/2 values are attributable principally to differences in the basicity of the equatorial ligands. Differences in rate constants are considered within the context of Marcus theory of electron transfer, but no specific structural change(s) in the complexes between the two oxidation states can be uniquely identified with the underlying variability in the heterogeneous rate constants and electron-transfer coefficients." @default.
• W2060492363 created "2016-06-24" @default.
• W2060492363 creator A5030873133 @default.
• W2060492363 date "2002-05-31" @default.
• W2060492363 modified "2023-09-25" @default.
• W2060492363 title "Redox Energetics and Kinetics of Uranyl Coordination Complexes in Aqueous Solution" @default.
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• W2060492363 doi "https://doi.org/10.1021/ic0201708" @default.
• W2060492363 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12079476" @default.
• W2060492363 hasPublicationYear "2002" @default.
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