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- W2060522024 abstract "Abstract It was believed that electroosmotic mobility μ eo is inversely proportional to the square root of the ionic strength I . But the linear relationship for regression analysis was expressed differently in different papers. The paper studied the linear expression of the mathematical relationship between μ eo and c (background buffer concentration) by mathematical transform and real experimental data. μ eo values of fused silica capillary were determined in four buffer systems. Their experimental conditions were controlled carefully for decreasing temperature difference Δ T and pH difference ΔpH in 50 µm ID capillary, in which no double layer overlap existed. The linear relationship between the reciprocal of electroosmotic mobility and the square root of concentration (or ionic strength) was derived by mathematical method. The regression analysis of experimental data was shown to well correspond to the relationship. The constants in regression equation could be well defined and the calculated results were acceptable." @default.
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- W2060522024 date "2006-01-01" @default.
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- W2060522024 title "Linear Expression of the Mathematical Relationship between Electroosmotic Mobility and Buffer Concentration" @default.
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- W2060522024 doi "https://doi.org/10.1002/cjoc.200690026" @default.
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