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- W2060563197 abstract "Several phenyl alkyl ketones display two overlapping short-lived phosphorescences at 77°K, with 0—0 bands at 384 nm (74.5 kcal) and 397 nm (72.0 kcal). The higher energy emission (τ = 5–10 msec) is favored in rigid methylcyclohexane glasses, while the proportion of lower-energy emission (τ = 4–5 msec) increases with increasing amounts of 2-methylbutane in the glass. In both isopentane at 77°K and benzene solution at room temperature, only the lower-energy spectrum is evident. The higher-energy emission is ascribed to n,π* triplets rigidly held in ground state conformations, while the lower-energy emission is assigned to conformationally-relaxed n,π* triplets." @default.
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- W2060563197 date "1972-04-01" @default.
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- W2060563197 title "Viscosity-dependent dual phosphorescence of phenyl alkyl ketones" @default.
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- W2060563197 doi "https://doi.org/10.1016/0009-2614(72)85007-3" @default.
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