FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2060565229> ?p ?o ?g. }

• W2060565229 endingPage "390" @default.
• W2060565229 startingPage "383" @default.
• W2060565229 abstract "The frequency of the 7F0→5D0 transition of Eu3+ is found to correlate with the sum of derived nephelauxetic parameters of the ligating atoms in Eu3+ complexes. Parameters for nine distinct coordinating atom types are obtained via a multiple linear regression method applied to experimental 7F0→5D0 transition frequencies of twenty-seven 9-coordinate Eu3+ complexes with known ligand constituents. The linear correlation coefficient is 0.99. Addition of data from 7-, 8-, 10-, and 11-coordinate complexes and use of a multiplicative constant, characteristic of each coordination number, produces a second linear correlation covering thirty-seven systems with a correlation coefficient of 0.98. The present approach seeks to understand the factors which influence the 7F0→5D0 transition frequency and to make predictions of this quantity for particular ligand environments. It is completely empirical in nature; however, the results may be understood in terms of an underlying theoretical cause. The parameters obtained here correlate roughly with the nephelauxetic h-values of Jørgensen for the few cases where appropriate ligand matches are available. The 7F0→5D0 term separation will decrease from its free-ion value of 17 374 cm−1 with increasing Eu3+ -ligand covalency, and the presently derived parameters are consistent with this idea. The correlation presented here is clearly superior to our earlier attempt to identify a relationship between the 7F0→5D0 transition frequency and the total formal charge on the ligands in a complex." @default.
• W2060565229 created "2016-06-24" @default.
• W2060565229 creator A5008914681 @default.
• W2060565229 creator A5023476802 @default.
• W2060565229 date "1995-02-01" @default.
• W2060565229 modified "2023-10-16" @default.
• W2060565229 title "On correlating the frequency of the 7F0 → 5D0 transition in Eu3+ complexes with the sum of ‘nephelauxetic parameters’ for all of the coordinating atoms" @default.
• W2060565229 cites W1541000911 @default.
• W2060565229 cites W1965167554 @default.
• W2060565229 cites W1965400623 @default.
• W2060565229 cites W1967217192 @default.
• W2060565229 cites W1970803380 @default.
• W2060565229 cites W1970882627 @default.
• W2060565229 cites W1976557490 @default.
• W2060565229 cites W1985042824 @default.
• W2060565229 cites W1985797474 @default.
• W2060565229 cites W1994638130 @default.
• W2060565229 cites W1995441638 @default.
• W2060565229 cites W2001649278 @default.
• W2060565229 cites W2005410940 @default.
• W2060565229 cites W2007862804 @default.
• W2060565229 cites W2015250942 @default.
• W2060565229 cites W2015548956 @default.
• W2060565229 cites W2017759574 @default.
• W2060565229 cites W2020321624 @default.
• W2060565229 cites W2022814613 @default.
• W2060565229 cites W2024580269 @default.
• W2060565229 cites W2026394191 @default.
• W2060565229 cites W2035021074 @default.
• W2060565229 cites W2042299493 @default.
• W2060565229 cites W2047581364 @default.
• W2060565229 cites W2048101129 @default.
• W2060565229 cites W2053439307 @default.
• W2060565229 cites W2076468164 @default.
• W2060565229 cites W240949504 @default.
• W2060565229 cites W3004526035 @default.
• W2060565229 cites W3004736022 @default.
• W2060565229 cites W3138406080 @default.
• W2060565229 cites W4235732797 @default.
• W2060565229 doi "https://doi.org/10.1016/0020-1693(94)04269-2" @default.
• W2060565229 hasPublicationYear "1995" @default.
• W2060565229 type Work @default.
• W2060565229 sameAs 2060565229 @default.
• W2060565229 citedByCount "239" @default.
• W2060565229 countsByYear W20605652292012 @default.
• W2060565229 countsByYear W20605652292013 @default.
• W2060565229 countsByYear W20605652292014 @default.
• W2060565229 countsByYear W20605652292015 @default.
• W2060565229 countsByYear W20605652292016 @default.
• W2060565229 countsByYear W20605652292017 @default.
• W2060565229 countsByYear W20605652292018 @default.
• W2060565229 countsByYear W20605652292019 @default.
• W2060565229 countsByYear W20605652292020 @default.
• W2060565229 countsByYear W20605652292021 @default.
• W2060565229 countsByYear W20605652292022 @default.
• W2060565229 countsByYear W20605652292023 @default.
• W2060565229 crossrefType "journal-article" @default.
• W2060565229 hasAuthorship W2060565229A5008914681 @default.
• W2060565229 hasAuthorship W2060565229A5023476802 @default.
• W2060565229 hasConcept C105795698 @default.
• W2060565229 hasConcept C116569031 @default.
• W2060565229 hasConcept C121332964 @default.
• W2060565229 hasConcept C134306372 @default.
• W2060565229 hasConcept C145148216 @default.
• W2060565229 hasConcept C147597530 @default.
• W2060565229 hasConcept C147789679 @default.
• W2060565229 hasConcept C149635348 @default.
• W2060565229 hasConcept C170493617 @default.
• W2060565229 hasConcept C178790620 @default.
• W2060565229 hasConcept C185592680 @default.
• W2060565229 hasConcept C2780092901 @default.
• W2060565229 hasConcept C2989041947 @default.
• W2060565229 hasConcept C3019152653 @default.
• W2060565229 hasConcept C33923547 @default.
• W2060565229 hasConcept C41008148 @default.
• W2060565229 hasConcept C42747912 @default.
• W2060565229 hasConcept C48921125 @default.
• W2060565229 hasConcept C55493867 @default.
• W2060565229 hasConcept C58312451 @default.
• W2060565229 hasConcept C97355855 @default.
• W2060565229 hasConceptScore W2060565229C105795698 @default.
• W2060565229 hasConceptScore W2060565229C116569031 @default.
• W2060565229 hasConceptScore W2060565229C121332964 @default.
• W2060565229 hasConceptScore W2060565229C134306372 @default.
• W2060565229 hasConceptScore W2060565229C145148216 @default.
• W2060565229 hasConceptScore W2060565229C147597530 @default.
• W2060565229 hasConceptScore W2060565229C147789679 @default.
• W2060565229 hasConceptScore W2060565229C149635348 @default.
• W2060565229 hasConceptScore W2060565229C170493617 @default.
• W2060565229 hasConceptScore W2060565229C178790620 @default.
• W2060565229 hasConceptScore W2060565229C185592680 @default.
• W2060565229 hasConceptScore W2060565229C2780092901 @default.
• W2060565229 hasConceptScore W2060565229C2989041947 @default.
• W2060565229 hasConceptScore W2060565229C3019152653 @default.
• W2060565229 hasConceptScore W2060565229C33923547 @default.
• W2060565229 hasConceptScore W2060565229C41008148 @default.
• W2060565229 hasConceptScore W2060565229C42747912 @default.
• W2060565229 hasConceptScore W2060565229C48921125 @default.

• next