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- W2060568476 abstract "A solvent extraction, flame atomic absorption analytical scheme is reported for the elements Au, Tl, Sb, Ga, Mo, Cu, Ni, Co, Ag, Bi, Cd, Pb, Zn and Mn in geological materials. Results are quoted for NIM standard rocks and for USGS reference samples, and are compared with published values; practical detection limits are generally better than 0.2 ppm. A stepwise solvent extraction and preconcentration process is utilised (chloro complexes, diethyldithiocarbamate and 8-hydroxyquinoline chelates are used with methyl isobutyl ketone and n-butyl acetate as solvents) which allows the reproducible isolation of groups of elements which generally occur at similar concentrations geologically. Analytical accuracy is maintained by the chemical elimination, within each step, of other chelate-forming elements present at higher concentrations which would cause spectral interferences during the atomic absorption measurements. The complete stepwise process is reported together with elemental partition data which covers a range of aqueous ionic conditions." @default.
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- W2060568476 date "1978-11-01" @default.
- W2060568476 modified "2023-09-26" @default.
- W2060568476 title "Improved stepwise solvent extraction scheme for geochemical trace analysis using flame atomic absorption" @default.
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- W2060568476 doi "https://doi.org/10.1016/0375-6742(78)90016-x" @default.
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