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- W2060602286 abstract "The cis and trans isomers of 3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-methylthiomethylene-α-D-xylo- and -α-D-ribo-hexofuranoses have been prepared by treatment of 1,2:5,6-di-O-isopropylidene-α-D-xylo- and -α-D-ribo-hexofuran-3-uloses with methylthiomethylene-triphenylphosphorane. Configurations are assigned by NMR. A new type of 4J is described. Hydrogenation-desulfurization of the methylthiovinylic sugars affords 3-deoxy-3-methyl sugars of the D-allo, D-gulo, and D-galacto series. Derivatives of 3-deoxy-3-methyl-D-lyxose and 3-deoxy-3-methyl-D-ribose are prepared by chain-shortening of derivatives of the corresponding 3-deoxy-3-methyl-hexoses." @default.
- W2060602286 created "2016-06-24" @default.
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- W2060602286 date "1970-01-01" @default.
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- W2060602286 title "Utilisation d'ylides du phosphore non stabilis�s en chimie des sucres VI. Sucres ramifi�s d�riv�s des di-O-isopropylid�ne-1,2:5,6-?-D-ribo-et-?-D-xylo-hexofurannosul-3-oses" @default.
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- W2060602286 doi "https://doi.org/10.1002/hlca.19700530629" @default.
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