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• W2060654131 startingPage "1136" @default.
• W2060654131 abstract "The low-temperature properties of a family of ytterbium-based compounds with the composition ${mathrm{Yb}}_{2}{T}_{3}{X}_{9}$ $(T=mathrm{Rh}, mathrm{Ir}; X=mathrm{Al}, mathrm{Ga})$ are studied by means of magnetic susceptibility, electrical resistivity, thermoelectric power, and specific-heat ${C}_{P}$ measurements. ${mathrm{Yb}}_{2}{mathrm{Rh}}_{3}{mathrm{Al}}_{9}$ and ${mathrm{Yb}}_{2}{mathrm{Ir}}_{3}{mathrm{Al}}_{9}$ show the typical properties of heavy-fermion antiferromagnets, namely they order at ${T}_{N}=3.5 mathrm{K}$ and ${T}_{N}=5.5 mathrm{K},$ respectively, their ${C}_{P}/T$ data extrapolate to ${ensuremath{gamma}}_{o}=230 mathrm{mJ}/mathrm{mol} mathrm{Yb} {mathrm{K}}^{2}$ below 0.5 K, and their entropy gain at ${T}_{N}$ reaches $0.6Rmathrm{ln}2$ only. The transport data show evidence of low-lying crystal-electric-field levels separated by ${ensuremath{Delta}}_{mathrm{CEF}}ensuremath{simeq}30 mathrm{K}$ from the ground-state doublet. On the contrary, ${mathrm{Yb}}_{2}{mathrm{Rh}}_{3}{mathrm{Ga}}_{9}$ and ${mathrm{Yb}}_{2}{mathrm{Ir}}_{3}{mathrm{Ga}}_{9}$ show mixed-valent behavior, as observed in most Yb-based intermetallics. The effect of the ligands on the ground-state properties is discussed and compared with other lanthanide- and actinide-based isostructural ${R}_{2}{T}_{3}{X}_{9}$ homologues." @default.
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• W2060654131 date "1999-07-01" @default.
• W2060654131 modified "2023-10-16" @default.
• W2060654131 title "Magnetic, transport, and thermal properties of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Yb</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>T</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>X</mml:mi></mml:mrow><mml:mrow><mml:mn>9</mml:mn></mml:mrow></mml:msub></mml:…" @default.
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• W2060654131 doi "https://doi.org/10.1103/physrevb.60.1136" @default.
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