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• W2060668007 abstract "Sterically crowded chiral biaryl ketimines have been prepared via nucleophilic addition onto a substituted benzonitrile or 8-cyanoquinoline and subsequent treatment of the resulting methylenimines either with methyl iodide, or with a chiral primary amine. Atropisomerism due to the hindered rotation of the aryl groups about the C–C bond adjacent to CN has been evidenced in all cases. Physical separation and full characterisation (NMR and X-ray analysis) of atropisomeric imines have been accomplished." @default.
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• W2060668007 date "2008-07-01" @default.
• W2060668007 modified "2023-10-18" @default.
• W2060668007 title "Synthesis, separation and structure determination of atropisomeric ketimines: precursors of new potential chiral ligands and phase-transfer catalysts" @default.
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• W2060668007 doi "https://doi.org/10.1016/j.tetasy.2008.06.024" @default.
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