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- W2060705953 abstract "The general instability of desoxy-isoalloxazines has been confirmed by studying the formation and decomposition of 4-phenyl-4-desoxy-isoalloxazines and -alloxazines. It has been shown, that the former (4-desoxy-flavins) may be synthesized in the semiquinonoid radical state. These radicals react with O2 or H2O2 with fission of the 4-substituents to give the analogous 4-oxo-compounds by a hydroperoxide rearrangement. In view of this instability, the oxinate like structure of flavin metal chelates may be excluded." @default.
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- W2060705953 date "1960-01-01" @default.
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- W2060705953 title "Studien in der Lumiflavin-Reihe VII. Zur Kenntnis der 4-Desoxyflavine und der Struktur von Flavin-Metallchelaten" @default.
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- W2060705953 doi "https://doi.org/10.1002/hlca.19600430150" @default.
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