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- W2060706176 abstract "The title compound, {[PtIIPtIVI2(C2H8N2)4](HPO4)(H2PO4)I·3H2O}n, has a chain structure composed of square-planar [Pt(en)2]2+ and elongated octahedral trans-[PtI2(en)2]2+ cations (en is ethylenediamine) stacked alternately along the c axis and bridged by the I atoms; a three-dimensionally valence-ordered system exists with respect to the Pt sites. The title compound also has a unique cyclic tetramer structure composed of two hydrogenphosphate and two dihydrogenphosphate ions connected by strong hydrogen bonds [O⋯O = 2.522 (10), 2.567 (10) and 2.569 (11) Å]. The Pt and I atoms form a zigzag ⋯I—PtIV—I⋯PtII⋯ chain, with PtIV—I bond distances of 2.6997 (7) and 2.6921 (7) Å, interatomic PtII⋯I distances of 3.3239 (8) and 3.2902 (7) Å, and PtIV—I⋯PtII angles of 154.52 (3) and 163.64 (3)°. The structural parameters indicating the mixed-valence state of platinum, expressed by δ = (PtIV—I)/(PtII—I), are 0.812 and 0.818 for the two independent I atoms." @default.
- W2060706176 created "2016-06-24" @default.
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- W2060706176 date "2006-01-14" @default.
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- W2060706176 title "A one-dimensional iodine-bridged Pt<sup>II</sup>/Pt<sup>IV</sup>mixed-valence complex,<i>catena</i>-poly[[[bis(ethylenediamine)platinum(II)]-μ-iodo-[bis(ethylenediamine)platinum(IV)]-μ-iodo] hydrogenphosphate dihydrogenphosphate iodide trihydrate]" @default.
- W2060706176 doi "https://doi.org/10.1107/s0108270105041247" @default.
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