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• W2060714725 abstract "Polyvinyl chloride (PVC) formulated with two different stabilizer systems (Ca/Zn stearates and dibasic lead phthalate) irradiated at 75 kGy at two different dose rates were studied in order to evaluate their effect in thermal stability. Samples were degraded in a TGA instrument at different heating rates and the activation energy (Ea) to dehydrochlorination was calculated using the Arrhenius method in accordance with ASTM E 1641-07. TGA evaluations show that temperature for HCl evolution is higher when increasing heating rate, as well as higher resistance to degradation, for irradiated lead formulations; however, after activation energies calculation the irradiated Ca/Zn formulations are more stable. The controversial results are due to the low initial stability of lead additives in PVC." @default.
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• W2060714725 date "2014-04-01" @default.
• W2060714725 modified "2023-09-26" @default.
• W2060714725 title "Thermal stability of PVC formulations gamma irradiated at different dose rates" @default.
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• W2060714725 doi "https://doi.org/10.1016/j.radphyschem.2013.11.004" @default.
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