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- W2060742705 endingPage "5179" @default.
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- W2060742705 abstract "Group 4 metal complexes [M(η5-C5Me4SiMe2-η1-N-2R)(NMe2)2] (R = pyridine, pyrazine, pyrimidine, thiazole, M = Ti; R = pyridine, thiazole; M = Zr) containing the tetramethylcyclopentadienyl-dialkylsilyl bridged amidinato as pendant ligand, were synthesized and characterized by elemental analysis, solution 1H, 13C and 15N NMR spectroscopy and experimental 13C and 15N CPMAS in the solid state. The crystal structures of [Ti(η5-C5Me4SiMe2-η1-N-2R)(NMe2)2] (R = pyridine 2a, pyrazine 2b, pyrimidine 2c, thiazole 2d) were determined by single crystal X-ray diffraction studies. All compounds exhibit a distorted tetrahedral geometry, with the ansa-monocyclopentadienyl-amido ligands acting in a bidentate mode. The [M(η5-C5Me4SiMe2-η1-N-2R)(NMe2)2] (R = pyridine, thiazole; M = Zr, Ti) complexes are ethylene polymerization catalysts in the presence of MAO and they are active precursors in regioselective catalytic hydroamination operating with an anti-Markovnikov mechanism." @default.
- W2060742705 created "2016-06-24" @default.
- W2060742705 creator A5003052337 @default.
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- W2060742705 creator A5050800364 @default.
- W2060742705 date "2007-01-01" @default.
- W2060742705 modified "2023-10-17" @default.
- W2060742705 title "Synthesis, characterization and reactivity of new complexes of titanium and zirconium containing a potential tridentate amidinato-cyclopentadienyl ligand" @default.
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- W2060742705 doi "https://doi.org/10.1039/b709923a" @default.
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