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- W2060756906 abstract "Voltammetric data for oxidation of Bu 4 N + Cl − , ClO 2 , and Et 4 N + ClO 4 − in CH 3 CN, Et 4 N + BF 4 − at platinum are reported. Acetamidation of methyl hexanoate and methyl butyrate results when these chlorine containing species are preparatively oxidized in CH 3 CN. This acetamidation also results from oxidation of mixtures of methyl hexanoate and Et 4 N + BF 4 − in CH 3 CN at 3.1 V. The yield ratio of isomers, methyl 5-acetamidohexanoate and methyl 4-acetamidohexanoate obtained from methyl hexanoate are independent of the species (Cl − , ClO 2 , ClO 4 − ) initially oxidized. A mechanism involving radicals derived from the solvent/electrolyte is proposed." @default.
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- W2060756906 date "1976-09-01" @default.
- W2060756906 modified "2023-09-25" @default.
- W2060756906 title "Anodic acetamidation via ClO4−, Cl− and ClO2 oxidation" @default.
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