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- W2060778885 abstract "A general synthesis of chiral 4-amino-4,5-dihydro-3H-dinaphthophosphepines 5a–f is described. The resulting monodentate chiral aminophosphinites have been tested in the rhodium-catalyzed asymmetric hydrogenation of methyl α-acetamidocinnamate and methyl α-acetamidoacrylate. Enantioselectivities up to 96% ee were obtained in the presence of 5a and sodium dodecylsulfonate in toluene." @default.
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- W2060778885 date "2003-05-01" @default.
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- W2060778885 title "Synthesis of new chiral monodentate aminophosphinites and their use in catalytic asymmetric hydrogenations" @default.
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- W2060778885 doi "https://doi.org/10.1016/s0022-328x(03)00223-7" @default.
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