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• W2060816482 abstract "Abstract The orientation dependence of three independent 23Na relaxation rates is determined from measurements on the counterions in a magnetically aligned hexagonal lyotropic liquid crystal. The data allow us to determine the nine director-frame spectral densities that comprise the full information content of the spin-relaxation behavior of a quadrupolar nucleus in a uniaxial phase. The model-independent director-frame spectral densities provide important information about the time scale and rotational symmetry of the anisotropic motions in the phase. More detailed information is obtained by invoking a specific dynamic model that separates dynamic and structural factors. The six high-frequency spectral densities are quantitatively accounted for in terms of fast local motions and counterion surface diffusion around the cylindrical surfactant aggregates, while the three zero-frequency spectral densities contain large contributions from diffusion-modulated director fluctuations." @default.
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• W2060816482 date "1992-11-01" @default.
• W2060816482 modified "2023-09-27" @default.
• W2060816482 title "Anisotropic 23Na spin relaxation in liquid crystals. Determination of all nine spectral densities for a hexagonal lyotropic phase" @default.
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• W2060816482 doi "https://doi.org/10.1016/0022-2364(92)90261-5" @default.
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