FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2060849206> ?p ?o ?g. }

• W2060849206 endingPage "4158" @default.
• W2060849206 startingPage "4154" @default.
• W2060849206 abstract "Abstract The tetramethyl ester of (hydroxy)(phenyl)methylenebis(phosphonic acid) reacts with morpholinosulfur trifluoride (MOST) to provide, along with the expected product of the substitution of a hydroxy group by fluorine, the adduct of (morpholino)(phenyl)carbene with PF 5 , compound 3a . Fluorination of dimethyl α‐aroylphosphonates with MOST yields adducts of (amino)(aryl)carbene with PF 5 ( p ‐XC 6 H 4 )(Morph)C:→PF 5 [ 3a – f , where Morph is morpholyl, X = H ( a ), Me ( b ), OEt ( c ), F ( d ), Cl ( e ), CF 3 ( f )] as the major reaction products. The reaction mechanism proposed is based on experimental data and DFT calculations. The structure of adduct 3a was determined by X‐ray studies. Hydrolysis of compounds 3e and 3f , bearing substituents Cl and CF 3 on the phenyl ring, respectively, yields previously unknown benzoylpentafluorophosphates [ p ‐XC 6 H 4 –C(=O)PF 5 ] – MorphH + ." @default.
• W2060849206 created "2016-06-24" @default.
• W2060849206 creator A5013330080 @default.
• W2060849206 creator A5041191571 @default.
• W2060849206 creator A5070334233 @default.
• W2060849206 creator A5073222759 @default.
• W2060849206 creator A5075981542 @default.
• W2060849206 creator A5088808822 @default.
• W2060849206 date "2013-07-16" @default.
• W2060849206 modified "2023-10-16" @default.
• W2060849206 title "Simple Route to Adducts of (Amino)(aryl)carbene with Phosphorus Pentafluoride" @default.
• W2060849206 cites W1862785984 @default.
• W2060849206 cites W1970715720 @default.
• W2060849206 cites W1978231694 @default.
• W2060849206 cites W1989160606 @default.
• W2060849206 cites W1992582121 @default.
• W2060849206 cites W1995507794 @default.
• W2060849206 cites W1996848424 @default.
• W2060849206 cites W2007020826 @default.
• W2060849206 cites W2008567437 @default.
• W2060849206 cites W2021443577 @default.
• W2060849206 cites W2025917757 @default.
• W2060849206 cites W2031485027 @default.
• W2060849206 cites W2032719166 @default.
• W2060849206 cites W2033043158 @default.
• W2060849206 cites W2035081650 @default.
• W2060849206 cites W2039346098 @default.
• W2060849206 cites W2044945053 @default.
• W2060849206 cites W2048845652 @default.
• W2060849206 cites W2055563809 @default.
• W2060849206 cites W2058210956 @default.
• W2060849206 cites W2067718414 @default.
• W2060849206 cites W2075434237 @default.
• W2060849206 cites W2079935930 @default.
• W2060849206 cites W2082011669 @default.
• W2060849206 cites W2091455514 @default.
• W2060849206 cites W2139175722 @default.
• W2060849206 cites W2142670098 @default.
• W2060849206 cites W2146798438 @default.
• W2060849206 cites W2171169866 @default.
• W2060849206 cites W2320813712 @default.
• W2060849206 cites W2783103906 @default.
• W2060849206 cites W2951230211 @default.
• W2060849206 cites W4236729606 @default.
• W2060849206 doi "https://doi.org/10.1002/ejic.201300563" @default.
• W2060849206 hasPublicationYear "2013" @default.
• W2060849206 type Work @default.
• W2060849206 sameAs 2060849206 @default.
• W2060849206 citedByCount "10" @default.
• W2060849206 countsByYear W20608492062014 @default.
• W2060849206 countsByYear W20608492062015 @default.
• W2060849206 countsByYear W20608492062016 @default.
• W2060849206 countsByYear W20608492062018 @default.
• W2060849206 countsByYear W20608492062019 @default.
• W2060849206 countsByYear W20608492062022 @default.
• W2060849206 crossrefType "journal-article" @default.
• W2060849206 hasAuthorship W2060849206A5013330080 @default.
• W2060849206 hasAuthorship W2060849206A5041191571 @default.
• W2060849206 hasAuthorship W2060849206A5070334233 @default.
• W2060849206 hasAuthorship W2060849206A5073222759 @default.
• W2060849206 hasAuthorship W2060849206A5075981542 @default.
• W2060849206 hasAuthorship W2060849206A5088808822 @default.
• W2060849206 hasConcept C108204754 @default.
• W2060849206 hasConcept C155647269 @default.
• W2060849206 hasConcept C161790260 @default.
• W2060849206 hasConcept C178790620 @default.
• W2060849206 hasConcept C185592680 @default.
• W2060849206 hasConcept C2777164566 @default.
• W2060849206 hasConcept C2780263894 @default.
• W2060849206 hasConcept C2781076698 @default.
• W2060849206 hasConcept C506198293 @default.
• W2060849206 hasConcept C71240020 @default.
• W2060849206 hasConcept C94412978 @default.
• W2060849206 hasConceptScore W2060849206C108204754 @default.
• W2060849206 hasConceptScore W2060849206C155647269 @default.
• W2060849206 hasConceptScore W2060849206C161790260 @default.
• W2060849206 hasConceptScore W2060849206C178790620 @default.
• W2060849206 hasConceptScore W2060849206C185592680 @default.
• W2060849206 hasConceptScore W2060849206C2777164566 @default.
• W2060849206 hasConceptScore W2060849206C2780263894 @default.
• W2060849206 hasConceptScore W2060849206C2781076698 @default.
• W2060849206 hasConceptScore W2060849206C506198293 @default.
• W2060849206 hasConceptScore W2060849206C71240020 @default.
• W2060849206 hasConceptScore W2060849206C94412978 @default.
• W2060849206 hasIssue "24" @default.
• W2060849206 hasLocation W20608492061 @default.
• W2060849206 hasOpenAccess W2060849206 @default.
• W2060849206 hasPrimaryLocation W20608492061 @default.
• W2060849206 hasRelatedWork W1964886857 @default.
• W2060849206 hasRelatedWork W1990749895 @default.
• W2060849206 hasRelatedWork W2022671731 @default.
• W2060849206 hasRelatedWork W2111526125 @default.
• W2060849206 hasRelatedWork W2145739361 @default.
• W2060849206 hasRelatedWork W2495840652 @default.
• W2060849206 hasRelatedWork W2950193256 @default.
• W2060849206 hasRelatedWork W3180379284 @default.
• W2060849206 hasRelatedWork W3208134792 @default.
• W2060849206 hasRelatedWork W4205252703 @default.

• next