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• W2060865102 abstract "Cross sections have been calculated for the scattering of slow electrons by water and methane molecules. A simple model is used: scattering is from a rigid molecule, exchange and polarisation effects are included in an approximate way, exchange by orthogonalising the scattered electron function to bound orbitals of the same symmetry and polarisation by using a potential correct at large distances but with an ad hoc short range cut-off parameter; the short range static interaction is, however, obtained from SCF target wavefunctions. Total, momentum-transfer and differential cross sections are given for CH4. In this body-fixed approximation total cross sections are undefined for molecules with a permanent dipole moment such as H2O and H2S; results are given here for momentum-transfer and differential cross sections of H2O. Possible negative-ion resonance states in H2O and H2S are discussed with reference to recent dissociative attachment and vibrational excitation experiments." @default.
• W2060865102 created "2016-06-24" @default.
• W2060865102 creator A5070600081 @default.
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• W2060865102 date "1980-02-14" @default.
• W2060865102 modified "2023-10-16" @default.
• W2060865102 title "The scattering of slow electrons by polyatomic molecules. A model study for CH₄, H₂O and H₂S" @default.
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• W2060865102 doi "https://doi.org/10.1088/0022-3700/13/3/022" @default.
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