Matches in SemOpenAlex for { <https://semopenalex.org/work/W2060889166> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2060889166 endingPage "201" @default.
- W2060889166 startingPage "194" @default.
- W2060889166 abstract "The decomposition of thiophen, furane and pyrrole on molybdenum disulphide catalysts occurs by two-point adsorption, which leads to a half-hydrogenated state from which the hetero-atom is then broken off. Retardation is caused by molecules also capable of giving two-point adsorption. Tetrahydrothiophen and tetrahydrofurane are decomposed on the same catalysts, but the mechanism is probably simpler. On nickel subsulphide catalysts, the tetrahydro-derivatives are decomposed much more easily than the unhydrogenated molecules, and they are held by single-point adsorption on the 111-plane of Ni 3 S 2 on which pairs of hydrogen atoms are also adsorbed. Thiophen and furane decompose by reaction with metallic nickel produced by reduction of Ni 3 S 2 . The nickel sulphide or oxide thus formed are subsequently reconverted to metal. Retardation of these changes arises from any reactant which can compete for nickel atoms, or which can cover the subsulphide surface and prevent its conversion to metal." @default.
- W2060889166 created "2016-06-24" @default.
- W2060889166 creator A5034519078 @default.
- W2060889166 creator A5050718999 @default.
- W2060889166 creator A5082857119 @default.
- W2060889166 date "1949-06-07" @default.
- W2060889166 modified "2023-10-16" @default.
- W2060889166 title "The catalytic decomposition of simple heterocyclic compounds II. Reaction kinetics and mechanism" @default.
- W2060889166 cites W1977668070 @default.
- W2060889166 cites W2010741282 @default.
- W2060889166 cites W2064359642 @default.
- W2060889166 cites W2101978215 @default.
- W2060889166 cites W2322323365 @default.
- W2060889166 doi "https://doi.org/10.1098/rspa.1949.0058" @default.
- W2060889166 hasPublicationYear "1949" @default.
- W2060889166 type Work @default.
- W2060889166 sameAs 2060889166 @default.
- W2060889166 citedByCount "10" @default.
- W2060889166 countsByYear W20608891662017 @default.
- W2060889166 crossrefType "journal-article" @default.
- W2060889166 hasAuthorship W2060889166A5034519078 @default.
- W2060889166 hasAuthorship W2060889166A5050718999 @default.
- W2060889166 hasAuthorship W2060889166A5082857119 @default.
- W2060889166 hasBestOaLocation W20608891661 @default.
- W2060889166 hasConcept C124681953 @default.
- W2060889166 hasConcept C147789679 @default.
- W2060889166 hasConcept C150394285 @default.
- W2060889166 hasConcept C161790260 @default.
- W2060889166 hasConcept C178790620 @default.
- W2060889166 hasConcept C179104552 @default.
- W2060889166 hasConcept C185592680 @default.
- W2060889166 hasConcept C192562407 @default.
- W2060889166 hasConcept C2779851234 @default.
- W2060889166 hasConcept C32909587 @default.
- W2060889166 hasConcept C504270822 @default.
- W2060889166 hasConcept C544153396 @default.
- W2060889166 hasConcept C549387045 @default.
- W2060889166 hasConcept C75473681 @default.
- W2060889166 hasConceptScore W2060889166C124681953 @default.
- W2060889166 hasConceptScore W2060889166C147789679 @default.
- W2060889166 hasConceptScore W2060889166C150394285 @default.
- W2060889166 hasConceptScore W2060889166C161790260 @default.
- W2060889166 hasConceptScore W2060889166C178790620 @default.
- W2060889166 hasConceptScore W2060889166C179104552 @default.
- W2060889166 hasConceptScore W2060889166C185592680 @default.
- W2060889166 hasConceptScore W2060889166C192562407 @default.
- W2060889166 hasConceptScore W2060889166C2779851234 @default.
- W2060889166 hasConceptScore W2060889166C32909587 @default.
- W2060889166 hasConceptScore W2060889166C504270822 @default.
- W2060889166 hasConceptScore W2060889166C544153396 @default.
- W2060889166 hasConceptScore W2060889166C549387045 @default.
- W2060889166 hasConceptScore W2060889166C75473681 @default.
- W2060889166 hasIssue "1049" @default.
- W2060889166 hasLocation W20608891661 @default.
- W2060889166 hasOpenAccess W2060889166 @default.
- W2060889166 hasPrimaryLocation W20608891661 @default.
- W2060889166 hasRelatedWork W1976638146 @default.
- W2060889166 hasRelatedWork W2011540288 @default.
- W2060889166 hasRelatedWork W2018229573 @default.
- W2060889166 hasRelatedWork W2057808024 @default.
- W2060889166 hasRelatedWork W2082266164 @default.
- W2060889166 hasRelatedWork W2312793164 @default.
- W2060889166 hasRelatedWork W2593445078 @default.
- W2060889166 hasRelatedWork W2767420283 @default.
- W2060889166 hasRelatedWork W2960871870 @default.
- W2060889166 hasRelatedWork W3034158708 @default.
- W2060889166 hasVolume "197" @default.
- W2060889166 isParatext "false" @default.
- W2060889166 isRetracted "false" @default.
- W2060889166 magId "2060889166" @default.
- W2060889166 workType "article" @default.