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- W2060902476 abstract "Abstract Ionic conductivity data for mixed Ag/Na-nitrite sodalites, AgxNa8−x(AlSiO4)6(NO2)2, have been determined over the temperature range 250 to 550°C in ambient atmosphere using an ac impedance method. The activation energy for conduction is reported for five samples with silver contents ranging from x=0 to 7.5 and was found to be a monotonic function of silver content, with a minimum at the highest silver content. Conductivity isotherms for the mixed Ag/Na nitrite sodalites were constructed, showing a direct relationship of total ionic conductivity as a function of silver content, with fastest ionic motion at the highest silver content. A transition of conduction mechanism from Na+ ion predominance to Ag+ ion predominance with increasing x was confirmed from variations in the interfacial impedance characteristics. Ionic conductivity of nitrite sodalites is strongly dependent upon the ionic radius of the mobile cations incorporated." @default.
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- W2060902476 date "1991-07-01" @default.
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- W2060902476 title "The ionic conductivity of (Ag, Na)-nitrite sodalites" @default.
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- W2060902476 doi "https://doi.org/10.1016/0167-2738(91)90236-5" @default.
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