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• W2060903180 abstract "Two new isostructural 1-D lanthanide coordination polymers, {[Ln(2,4-dcp)3(phen)] n [(Ln = Eu (1); Tb (2)], [2,4-dcp = 2,4-dichlorophenoxyacetate, phen = 1,10-phenanthroline], were obtained under hydrothermal conditions and characterized by IR spectroscopy, elemental analyses, thermogravimetry analyses, powder X-ray diffraction, and single-crystal X-ray diffraction. Both structures exhibit similar 1-D infinite chains with a {Ln2(2,4-dcp)6(phen)2} dimeric repeat unit, with lanthanides in an eight-coordinate environment. The results of thermal analysis indicate that 1 and 2 are quite stable to heat. 3-D fluorescence spectra of 1 and 2 were detected at room temperature under excitation and the emission wavelengths of 250–460 nm and 420–750 nm with the same interval of 5 nm, respectively. Interestingly, 1 and 2 possess longer fluorescence lifetimes than other complexes (τ = 1.61 ms for 1 at 611 nm; 1.79 ms for 2 at 543 nm)." @default.
• W2060903180 created "2016-06-24" @default.
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• W2060903180 date "2012-08-16" @default.
• W2060903180 modified "2023-09-23" @default.
• W2060903180 title "1-D Chain lanthanide coordination polymers based on mixed 2,4-dichlorophenoxyacetate and 1,10-phenanthroline ligands: crystal structures and luminescent properties" @default.
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• W2060903180 doi "https://doi.org/10.1080/00958972.2012.718337" @default.
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