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- W2060904405 abstract "Ring silicates (cyclosilicates) form a subgroup of oligosilicates. Cyclosilicates include isolated silicooxygen rings of different numbers of members in their structure. Isolated rings occur also in other structures described as cyclosilicate-like ones. In the present paper infrared and Raman study of cyclogermanates, cyclosilicates and cycloaluminosilicates have been carried out. Studies of SrO–SiO2, SrO–GeO2, BaO–GeO2, MgO–Al2O3–SiO2 systems allowed to show the influence of different, tetrahedral ring cations (Si+4, Al+3, Ge+4) on the ‘ring band’ positions. Presence of aluminium cations, lighter than silicon cations, causes the shift of ring band to higher wavenumbers. In the case of cyclogermanates, as there is the big mass difference between germanium and silicon, the ring band is observed in significantly lower wavenumber range. The examinations of cyclogermanates with different non-ring cations such as Sr+2 and Ba+2 can show the influence of these cations on the position of the bands." @default.
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- W2060904405 date "2001-09-01" @default.
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- W2060904405 title "FTIR studies of the cyclosilicate-like structures" @default.
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- W2060904405 doi "https://doi.org/10.1016/s0022-2860(01)00714-1" @default.
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