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- W2060908894 abstract "Fluorescence steady state and time-resolved studies of hydrophobically modified polyionene systems prepared by exchange reaction with counterions of aromatic and aliphatic character in the parent polymer were conducted in DMF and water solutions as well as in solid films cast from these solvents. The effect of polyionene composition on excimer formation and energy transfer has been examined for different types of counterions, that is: 1-pyrenesulfonate, 1-pyrenebutyrate, 2-naphthalene sulphonate and sodium dodecyl sulphate. In a DMF solution, excimer formation was observed only for hydrophobically modified parent polyionene samples. In an aqueous solution, excitation spectra and instantaneous decay of fluorescence monitored at 480 nm suggest that excimer originates from paired chromophores in the ground state. For solid samples prepared from different solvents, the results indicate that various structures produced by solvent as the result of the self-organising interactions may be trapped in the solid state by polyelectrolyte. Such findings might be interesting for a variety of new optically active materials." @default.
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- W2060908894 date "1998-05-01" @default.
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- W2060908894 title "Photophysical studies of functionalised polyionene complexes in solutions and in the solid state" @default.
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- W2060908894 doi "https://doi.org/10.1016/s1010-6030(98)00260-3" @default.
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