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- W2060914215 abstract "Six cadmium(II) compounds [Cd(Qnz) 2 (SCN) 2 ] n ( 1 ), [Cd(Qnz) 2 (dca) 2 ] n ( 2 ), [Cd(Qnz) 2 (N 3 ) 2 ]} n ( 3 ), [Cd 2 (μ-SCN-κ 2 N:S) 2 (SCN) 2 (Ptz) 4 (H 2 O) 2 ] ( 4 ), [Cd(Ptz) 2 (dca) 2 ] n ( 5 ) and [Cd(Ptz)(MeOH)(N 3 ) 2 ] n ( 6 ) were successfully synthesized and characterized by single-crystal diffraction. Additionally, the samples were characterized by powder X-ray diffraction (PXRD), thermal analysis and IR spectroscopy. The fluorescence properties of 1 , 2 , 3 , 5 and 6 were studied in solid state, while emission spectrum of 4 was recorded in methanolic solution. All they were compared with the fluorescence properties of the free ligands. Additionally, the electronic spectrum of 4 was investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ." @default.
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- W2060914215 date "2013-04-01" @default.
- W2060914215 modified "2023-10-16" @default.
- W2060914215 title "Syntheses, structures, thermal and luminescent properties of cadmium(II) complexes based on quinazoline and phthalazine" @default.
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- W2060914215 doi "https://doi.org/10.1016/j.poly.2013.02.016" @default.
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