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- W2060951519 endingPage "101" @default.
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- W2060951519 abstract "Reaction of nitroso compounds with metal-carbene complexes and metal carbonyls has been investigated. These reactions lead to reduction of the nitroso compounds, primarily to the corresponding azo- and azoxy compounds. Metal-nitrene complexes have been proposed as intermediates in these reactions. These intermediates couple rapidly with the unreacted nitroso compound, or enter into nitrene-like reactions with external or internal trapping agents. Reaction of metal carbonyls with nitrosoarenes and photolysis has been found to be an effective method for the reduction of nitrosoarenes to azoxyarenes, with few problems resulting from overreduction to amines or azo compounds." @default.
- W2060951519 created "2016-06-24" @default.
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- W2060951519 date "1989-05-01" @default.
- W2060951519 modified "2023-09-26" @default.
- W2060951519 title "Metathesis and reduction reactions of nitroso compounds with metal carbenes and metal carbonyls" @default.
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- W2060951519 doi "https://doi.org/10.1016/0022-328x(89)80121-4" @default.
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