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• W2060956871 endingPage "3346" @default.
• W2060956871 startingPage "3335" @default.
• W2060956871 abstract "The enantioselective synthesis of all four stereoisomers of the secondary metabolite 3-hydroxy-5-decanolide (4a) from Cephalosporium recifei and both enantiomers of massoialactone (5a) by starting from one chiral building block, streptenol A (1a), a secondary metabolite from Streptomyces sp., is described. The Key steps of the reaction sequence involve diastereoselective reduction of 1a to syn- or anti-triol 2a and 2b and the regioselective oxidation of the primary hydroxyl group. This reaction furnishes in one step the δ -lactones 3a and 3b and requires no protecting group." @default.
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• W2060956871 date "1991-01-01" @default.
• W2060956871 modified "2023-09-26" @default.
• W2060956871 title "Secondary metabolites by chemical screening -13. Enantioselective synthesis of δ-lactones from streptenola, achiral building block from streptomyces" @default.
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• W2060956871 doi "https://doi.org/10.1016/s0040-4020(01)86398-5" @default.
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