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- W2060963199 abstract "The Δv = 1 emission spectrum of the CH radical was observed by a Fourier transform spectrometer. The Herman-Wallis effect observed as intensity difference in P- and R-branch transitions was analyzed to give the transition dipole moment, where we used a new method to calculate intensities of vibration-rotation spectral lines with wave functions obtained by the diagonalization of a vibration-rotation energy matrix up to v = 40. When the permanent dipole moment of 1.46 D was used, the vibrational transition moment μ10 was determined to be -0.151(10) D, with 1 standard deviation in parentheses." @default.
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- W2060963199 date "1999-11-01" @default.
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- W2060963199 title "Vibrational Transition Moment of the CH Radical Determined from the Herman‐Wallis Effect" @default.
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