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- W2060970147 abstract "Polymerization of propylene by Cp * TiMe 2 (μ-Me)B(C 6 F 5 ) 3 in the presence of increasing partial pressures of H 2 results in ever decreasing polymer molecular weights, which is consistent with the hydrogenolytic chain transfer processes involving metal-polymer bonds in many heterogeneous and homogeneous systems. However, catalytic activities are not significantly increased as the extent of hydrogenolysis increases, unlike metallocene catalyst systems in which the H 2 reacts primarily with dormant catalytic sites containing propylene 2,1-insertion products. It was shown previously that monocyclopentadienyl systems do not become seriously deactivated following 2,1 insertions, and thus hydrogenolysis does not result in enhanced activities." @default.
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- W2060970147 date "1999-12-01" @default.
- W2060970147 modified "2023-09-27" @default.
- W2060970147 title "Effects of low hydrogen partial pressures on propylene polymerization by Cp*TiMe2(?-Me)B(C6F5)3" @default.
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- W2060970147 doi "https://doi.org/10.1002/(sici)1099-0518(19991201)37:23<4386::aid-pola15>3.0.co;2-s" @default.
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