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- W2060978029 abstract "Abstract Na 3 HSiO 4 ·2 H 2 O is dimorphic, the reversible transition point being found to be at 275 K with a very low heat of transition, Δ H t =0.52 kJ mol −1 . Both phases of Na 3 HSiO 4 ·2 H 2 O, the low-temperature or β-phase and the high-temperature or α-phase were successfully isolated and characterized by thermal and X-ray single crystal structure analysis. Both crystal structures being closely related and built of chains of [HSiO 4 ] 3− tetrahedra linked by SiOH⋯OSi— hydrogen bonds. Significant differences, however, appear in the H 2 O— surroundings, therefore giving rise to characteristic differences in their thermal behaviour." @default.
- W2060978029 created "2016-06-24" @default.
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- W2060978029 date "1984-09-01" @default.
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- W2060978029 title "Thermal studies on sodium silicate hydrates. III. Trisodium hydrogensilicate dihydrate, Na3HSiO4·2 H2O: Thermal stability, thermal decomposition reactions and dimorphism" @default.
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- W2060978029 doi "https://doi.org/10.1016/0040-6031(84)87110-5" @default.
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